Equilibrium modeling and kinetic studies on the adsorption of basic dye by a low-cost adsorbent: coconut (Cocos nucifera) bunch waste.

نویسندگان

  • B H Hameed
  • D K Mahmoud
  • A L Ahmad
چکیده

In this paper, the ability of coconut bunch waste (CBW), an agricultural waste available in large quantity in Malaysia, to remove basic dye (methylene blue) from aqueous solution by adsorption was studied. Batch mode experiments were conducted at 30 degrees C to study the effects of pH and initial concentration of methylene blue (MB). Equilibrium adsorption isotherms and kinetics were investigated. The experimental data were analyzed by the Langmuir, Freundlich and Temkin models of adsorption. The adsorption isotherm data were fitted well to Langmuir isotherm and the monolayer adsorption capacity was found to be 70.92 mg/g at 30 degrees C. The kinetic data obtained at different concentrations have been analyzed using a pseudo-first-order, pseudo-second-order equation and intraparticle diffusion equation. The experimental data fitted very well the pseudo-second-order kinetic model.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Equilibrium Modeling and Kinetic Studies on the Adsorption of Basic Dye by a Low Cost Adsorbent

An agricultural waste and eco-friendly biosorbent i.e. rice husk has been used as a cheap adsorbentfor the removal of methylene blue dye from aqueous solutions. The physical properties of the developedadsorbent were characterized using FTIR. The study was realized using batch experiments. The effectsof contact time, pH, initial dye concentration, biosorbent dose and temperature were investigate...

متن کامل

Direct Blue 71 Removal from Aqueous Solutions by Adsorption on Pistachio Hull Waste: Equilibrium, Kinetic and Thermodynamic Studies

Background and Purpose: Azo dyes including Direct Blue 71 (DB71) are toxic, mutagenic and carcinogenic contaminants in effluents of industries. This study aimed to investigate the adsorption of DB71 from aqueous solution onto pistachio hull waste (PHW) as a low-cost adsorbent. Materials and Methods: A series of experiments were performed via batch adsorption technique to examine the effect o...

متن کامل

KINETIC AND EQUILIBRIUM STUDIES OF ADSORPTION OF LEAD (II) IONS FROM AQUEOUS SOLUTION USING COIR DUST (Cocos nucifera L.) AND IT’S MODIFIED EXTRACT RESINS

Metal detoxification of waste water and industrial effluents are of increasing importance to industrialization in the twenty first century. The ability of coconut (cocos nucifera L) coir dust (CD), carbohydrate toluenediisocyanate resin (CTR) and sulphonated toluenediisocyanate resin (STR) to remove Pb(II) ions from aqueous solution by ion exchange was studied. Percentage ion exchange efficienc...

متن کامل

Optimization, Equilibrium and Kinetic Studies of Basic Red 2 Removal onto Waste Gossypium hirsutum Seeds

Cationic dye - basic red 2 (BR2) was removed from aqueous solutions by sulfuric acid activated waste Gossypium hirsutum seeds (WGSAB). The main and interactive effects of five process variables such as, adsorbent dose (1.25 – 5 g/L), initial dye concentration (100–300 mg/L), contact time (1–3 h),  pH (2 – 12) and temperature (20 – 400C) were investigated via  response su...

متن کامل

Adsorption of 5.5’-Disulfonicindigotin (5.5’-DI) onto Green Coconut Fiber (Cocos nucifera L.): Kinetic and Isotherms

Green coconut fiber (Cocos nucifera L.) has been largely used in solid-phase extraction. The effect of the initial dye concentration (1.91, 3.02 and 4.02) × 10−5 mol∙L−1 and solid phase contact (SPE) time were evaluated at different temperatures (283, 298 and 313) K at pH 2. Kinetic experimental data were applied to three simplified kinetic models: pseudo-first order, pseudo-second order, and i...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of hazardous materials

دوره 158 1  شماره 

صفحات  -

تاریخ انتشار 2008